Injection Molding Thermoplastic Polymers

Celazole® PBI has the highest heat resistance, wear resistance, strength and mechanical property retention of any engineered polymer on the planet.

Celazole® T-Series

PBI PAEK Polymer Compound – Superior polymer durability for your high performance thermoplastic needs

Celazole® T-Series products are PBI compounds designed for injection molding and extrusion. Combining the superior mechanical properties and thermal resistance of PBI with the melt process ability of polyaryletherketones (PEEK or PEKK), these products offer cost-effective high performance. These products are available in pellet form.

Celazole® PBI (polybenzimidazole) is a unique and highly stable heterocyclic polymer. PBI polymers are characterized by high thermal stability; exhibit high strength, broad chemical resistance and unique compatibility with certain other polymers including the polyaryletherketone family.

Celazole® T-Series Explained

T-Series products are composites of Celazole® PBI and polyarlyetherketones and come in formulations designed for some of the most demanding industrial, chemical, petrochemical and semiconductor applications imagined. At the heart of the Celazole® T-Series compound is Polybenzimidazole (PBI) – the world’s highest performing thermoplastic; a highly stable linear heterocyclic polymer known for its exceptionally high (427ºC) glass transition temperature, high strength, thermal stability and broad chemical resistance.

Tractability for injection molding and extrusion is obtained by compounding the PBI with polyetheretherketone (PEEK). Independently, PEEK is a high performance thermoplastic with excellent mechanical properties, chemical resistance and thermal stability, but when compounded with PBI, certain performance advantages of PBI carry through to the composite, while the processability of PEEK makes the products more functional.

Celazole® T-Series Value Proposition

The advantage of Celazole® T-Series over ordinary PEEK is the unexpected property set that results from the combination with PBI and other fillers (when present) that yield higher heat deflection temperatures (HDT), higher moduli, higher strength, improved wear resistance and lower creep. In the T-Series composites, HDT’s can be raised to 330ºC, just below the crystalline melting point of PEEK. The effect can be observed in the accompanying dynamic mechanical analysis (DMA) chart for TU-60 on this page.

A desirable balance of performance and tractability is obtained with the Celazole® T-Series products that place the group’s thermo-mechanical performance above PEEK, but below PBI. T-Series is designed for injection molding of parts that perform, but are cost effectively produced.

TU-60
TL-60
TF-60C
TF-60V
TK-60
TKL-60
TK-60C
Celazole® T-Series TU-60 is a high performance unfilled blend, ideal for applications requiring no fillers. This material works well for complex geometries and offers the best process ability. It is ideal for lamp sockets, connectors and backup seals.
Celazole® T-Series TL-60 is a lube grade blend offering superior wear resistance, low friction, chemical resistance and high load bearing capability. It’s well suited for rotor vanes, thrust bearings, plane bearings, bushings and other friction management applications – particularly under load.
Celazole® T-Series TF-60C is a carbon-reinforced blend, ideal for parts that require high strength, very low creep, and deflection resistance. A great match for planetary gears, office equipment, semiconductor, electronic and mechanical applications.
Celazole® T-Series TF-60V is a glass-reinforced blend offering thermal and electrical insulation, wear resistance and dimensional stability with the cost efficiency of a direct form process. An excellent choice for high temperature electrical insulators, plasma torch drag cup shields, swirl baffles and parts requiring minimal thermal expansion.
Celazole® T-Series TK-60 is an unreinforced melt processable blend of PBI-PEKK (polyetherketoneketone).
Celazole® T-Series TKL-60 is a self-lubricating melt processable blend of PBI-PEKK (polyetherketoneketone).
Celazole® T-Series TK-60C is a carbon fiber reinforced melt processable blend of PBI-PEKK (polyetherketoneketone).

Celazole® T-Series Applications

N

Bearing cages

N

Bushings

N

Compressor vanes

N

Conveyor systems

N

Dynamic load bearing components

N

Dynamic seals

N

Electrical connectors

N

End effector pads

N

Gears

N

Glass handling

N

Metal spinning rollers

N

Office equipment

N

Oilfield equipment

N

Oven conveyors

N

Piston rings

N

Plane bearings

N

Planetary gears

N

Plasma torch tips, insulators, swirl baffles

N

Pump bearings

N

Semiconductor wafer transportation

N

Sliding surfaces

N

Soldering equipment

N

Synchronizer rings

N

Temperature sensor housings

N

Textile equipment

N

Thrust washers

N

Tilt pad bearings

N

Turbines

N

Turbo charger bushings

N

Valve seats, stem seals, packings

Celazole® T-Series TU-60 Typical Properties (PBI PEEK Compound)
Unreinforced Melt Processable PBI

Celazole® T-Series TU-60 is a high performance unfilled blend, ideal for applications requiring no fillers. This material works well for complex geometries and offers the best process ability. It is ideal for lamp sockets, connectors and backup seals.

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

Compressive Strength

--- Modulus

THERMAL

Coefficient of Linear Thermal Expansion

--- 75‐300°F

--- 390‐570°F

Temperature of Initial (5%) Weight Loss In:

--- Air

--- Nitrogen

ASTM METHOD
D-638
D-790
D-695
TMA
TMA
TGA
TGA
ENGLISH VALUE
14.5 kpsi
730 kpsi
2.2%
25.4 kpsi
725 kpsi
30 kpsi
430 kpsi
19 X 10‐6 in/in°F
39 X 10‐6 in/in°F
930°F
930°F
METRIC VALUE
100mpA
5000 mpA
2.2%
175 mpA
5000 mpA
206 mpA
2900 mpA
34 µm/m°C
70 µm/m°C
499°C
499°C

Celazole® T-Series TL-60 Typical Properties (PBI PEEK Compound)
Self Lubricating Melt Processable PBI

Celazole® T-Series TL-60 is a lube grade blend offering superior wear resistance, low friction, chemical resistance and high load bearing capability. It’s well suited for rotor vanes, thrust bearings, plane bearings, bushings and other friction management applications – particularly under load.

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

Compressive Strength

--- Modulus

THERMAL

Coefficient of Linear Thermal Expansion

--- 75‐300°F

Heat Capacity @ 158°F

Heat Deflection Temperature

Temperature of Initial (5%) Weight Loss In:

--- Air

--- Nitrogen

Thermal Conductivity @ 70°F

ASTM METHOD
D-638
D-790
D-695
TMA
DSC
D-648
TGA
TGA
F-433
ENGLISH VALUE
14.5 kpsi
2650 kpsi
0.9%
27.6 kpsi
2320 kpsi
18 kpsi
740 kpsi
14 X 10‐6 in/in°F
0.28 Btu/lb°F
590°F
1116°F
1123°F
5.3 Btu in/hr•ft2°F
METRIC VALUE
120 MPa
18,300 MPa
0.9%
190 MPa
16,000 MPa
123 MPa
5100 MPa
26 µm/m°C
1160 J/kg°C
310°C
602°C
606°C
0.76 W/M°C

Celazole® T-Series TF-60C Typical Properties (PBI PEEK Compound)
Carbon Fiber Reinforced Melt Processable PBI

Celazole® T-Series TF-60C is a carbon-reinforced blend, ideal for parts that require high strength, very low creep, and deflection resistance. A great match for planetary gears, office equipment, semiconductor, electronic and mechanical applications.

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

Compressive Strength

--- Modulus

THERMAL

Coefficient of Linear Thermal Expansion

--- 75‐300°F

Heat Capacity @ 158°F

Heat Deflection Temperature @ 264 psi

Temperature of Initial (5%) Weight Loss In:

--- Air

--- Nitrogen

Thermal Conductivity @ 70°F

ASTM METHOD
D-638
D-790
D-695
TMA
DSC
D-648
TGA
TGA
F-433
ENGLISH VALUE
33 kpsi
3500 kpsi
1.4%
46.5 kpsi
3050 kpsi
32 kpsi
550 kpsi
14 X 10‐6 in/in°F
0.28 Btu/lb°F
608°F
1110°F
1160°F
3.1 Btu in/hr•ft2°F
METRIC VALUE
230 MPa
24,000 MPa
1.4%
320 MPa
21,000 MPa
220 MPa
3800 MPa
26 µm/m°C
1180 J/kg°C
320°C
599°C
627°C
0.39 kcal/mh°C

Celazole® T-Series TF-60V Typical Properties (PBI PEEK Compound)
Glass Fiber Reinforced Melt Processable PBI

Celazole® T-Series TF-60V is a glass-reinforced blend offering thermal and electrical insulation, wear resistance and dimensional stability with the cost efficiency of a direct form process. An excellent choice for high temperature electrical insulators, plasma torch drag cup shields, swirl baffles and parts requiring minimal thermal expansion.

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

Compressive Strength

--- Modulus

THERMAL

Coefficient of Linear Thermal Expansion

--- 75‐300°F

Heat Capacity @ 158°F

Heat Deflection Temperature @ 264 psi

Temperature of Initial (5%) Weight Loss In:

--- Air

--- Nitrogen

Thermal Conductivity @ 70°F

ASTM METHOD
D-638
D-790
D-695
TMA
DSC
D-648
TGA
TGA
F-433
ENGLISH VALUE
22 kpsi
1750 kpsi
1.4%
32.6 kpsi
1810 kpsi
32 kpsi
530 kpsi
9 X 10‐6 in/in°F
0.27 Btu/lb°F
590°F
1125°F
1175°F
2.5 Btu in/hr•ft2°F
METRIC VALUE
150 MPa
12,000 MPa
1.4%
225 MPa
121,500 MPa
220 MPa
3600 MPa
17 µm/m°C
1130 J/kg°C
310°C
607°C
635°C
0.31 kcal/mh°C

Celazole® T-Series TK-60 Typical Properties (PBI PEKK Compound)
Unreinforced Melt Processable PBI/PEKK

Celazole® T-Series TK-60 is an unreinforced melt processable blend of PBI-PEKK (polyetherketoneketone).

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

--- Elongation

ASTM METHOD
D-638
D-790
ENGLISH VALUE
14.5 kpsi
740 kpsi
2.2%
25.4 kpsi
755 kpsi
3.4%
METRIC VALUE
100 MPa
5,100 MPa
2.2%
175 MPa
5,200 MPa
3.4%

Celazole® T-Series TKL-60 Typical Properties (PBI PEKK Compound)
Self Lubricating Melt Processable PBI/PEKK

Celazole® T-Series TKL-60 is a self-lubricating melt processable blend of PBI-PEKK (polyetherketoneketone).

MECHANICAL

Tensile Strength

--- Modulus

--- Elongation

Flexural Strength

--- Modulus

--- Elongation

ASTM METHOD
D-638
D-790
ENGLISH VALUE
18 kpsi
2510 kpsi
1.0%
26 kpsi
2120 kpsi
1.3%
METRIC VALUE
125 MPa
17,300 MPa
1.0%
180 MPa
14,600 MPa
1.3%

Celazole® T-Series TK-60C Typical Properties (PBI PEKK Compound)
Carbon Fiber Reinforced Melt Processable PBI/PEKK

Celazole® T-Series TK-60C is a carbon fiber reinforced melt processable blend of PBI-PEKK (polyetherketoneketone).

MECHANICAL

Flexural Strength

--- Modulus

--- Elongation

ASTM METHOD
D-790
ENGLISH VALUE
44.2 kpsi
2600 kpsi
2.1%
METRIC VALUE
305 MPa
17,900 MPa
2.1%
Celazole® T-Series - Highest Heat Resistance & Strength
Celazole® T-Series - Highest Heat Resistance & Strength
Celazole® T-Series - Highest Heat Resistance & Strength
Celazole® T-Series - Highest Heat Resistance & Strength

Comparative Wear

In a thrust washer configuration wear test of competitive engineering plastics used in tribological applications, Celazole TL-60 proved itself an exceptional wear grade material. Over the range of 50 — 800 ft/min, TL-60 exhibited the lowest wear factors, the lowest coefficients of friction and the coolest counter-surface running temperatures in the group including wear grades of: polyetheretherketone (PEEK), polyamide-imide (PAI) and polyimide (PI).

Between 50 and 100,000 PV, the Wear Factors for wear grade PEEK were 4.6 times those of TL-60; wear grade PAI was 2.1 times higher; and wear grade PI 1.5 times higher than TL-60. The lower value (e.g. TL-60) is better, as a lower wear factor means less wear.

Because TL-60 is such a low friction material, it runs the coolest. That means longer part life. Between 50,000 and 100,000 PV across the full range of speeds, TL-60 ran nearly 100F cooler than wear grade PEEK; 50F cooler than wear grade PI; and more than 40F cooler than wear grade PAI. TL-60 is both strong and thermal resistant – making it the ideal choice for high load applications at moderate and low speeds. In the wear test, TL-60 was the only material to endure PV’s of 125,000 — 200,000 at the 50 ft/min speed and loads of 2500 — 4000 psi. The other materials failed by breaking or melting at these conditions.

Celazole® T-Series - Highest Heat Resistance & Strength
Celazole® T-Series - Highest Heat Resistance & Strength
Celazole® T-Series - Highest Heat Resistance & Strength

Celazole® is a registered trademark is a registered trademark of PBI Performance Products, Inc.

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Celazole® is a registered trademark of PBI Performance Products, Inc.

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This information and all further technical advice are based Polymics’ present knowledge and experience. However, neither Polymics Ltd nor any of its affiliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this information or its use. This information is for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right. The use of this product resides on the determination of the customer not Polymics Ltd. The customer must determine suitability of any information or material for any contemplated use, the manner of use and whether any patents are infringed. This information gives typical properties only and is not to be used for specification purposes. Polymics reserves the right to make additions, deletions, or modifications to the information at any time without prior notification.